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BERKELEY, CA / ARGONNE, IL – A team of Department of Energy (DOE) scientists at the Joint Center for Energy Storage Research (JCESR) has discovered the fastest magnesium-ion solid-state conductor, a major step towards making solid-state magnesium-ion batteries that are both energy dense and safe.

Argonne scientist Baris Key, shown on left at work in his nuclear magnetic resonance lab, worked with researchers at Berkeley Lab on the discovery of the fastest ever magnesium-ion solid-state conductor. (Credit: Argonne National Laboratory)

The electrolyte, which carries charge back and forth between the battery’s cathode and anode, is a liquid in all commercial batteries, which makes them potentially flammable, especially in lithium-ion batteries. A solid-state conductor, which has the potential to become an electrolyte, would be far more fire-resistant.

Researchers at DOE’s Lawrence Berkeley National Laboratory (Berkeley Lab) and Argonne National Laboratory were working on a magnesium battery, which offers higher energy density than lithium, but were stymied by the dearth of good options for a liquid electrolyte, most of which tend to be corrosive against other parts of the battery. “Magnesium is such a new technology, it doesn’t have any good liquid electrolytes,” said Gerbrand Ceder, a Berkeley Lab Senior Faculty Scientist. “We thought, why not leapfrog and make a solid-state electrolyte?”

The material they came up with, magnesium scandium selenide spinel, has magnesium mobility comparable to solid-state electrolytes for lithium batteries. Their findings were reported in Nature Communications in a paper titled, nike air force red women
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, a DOE Innovation Hub, sponsored the study, and the lead authors are Pieremanuele Canepa and Shou-Hang Bo, postdoctoral fellows at Berkeley Lab.

“With the help of a concerted effort bringing together computational materials science methodologies, synthesis, and a variety of characterization techniques, we have identified a new class of solid conductors that can transport magnesium ions at unprecedented speed,” Canepa said.

The research team also included scientists at MIT, who provided computational resources, and Argonne, who provided key experimental confirmation of the magnesium scandium selenide spinel material to document its structure and function.

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